How can I output the full PANTONE library on a PDF
Pantone does not provide a printable PDF for PANTONE colors. You can, however, use PANTONE Color Manager software, which has a style guide function allowing users to create individual PDF swatches for PANTONE Colors. You have the option to map the colors to an ICC output profile and generate device-specific CMYK data on each chip. The PDF swatches presumably can be assembled into a printable PDF document using Adobe Acrobat.
You may evaluate PANTONE Color Manager in trial mode for a 30-day period. Please review the article at http://www.pantone.com/help/?t=Activating%20PANTONE%20Color%20Manager%20in%20%27trial%20mode%27 for instructions.